[yuriyuri]

It depends on how you want to use it.

と links nouns together as a list.
In addition to this there is also とか、や、だの etc. which give a slightly different meaning.

そして just carries on from a previous sentence.
You could say in addition to this there are things like それに、それから etc.

There is the "て form"
言う　→　言って

There is the たり form (I think this could be translated as "and" in a way)
言う　→　言ったり

There are loads more but that is all I can think of, off the top of my head.

Since there is too much to explain in one post, I think you will get the best answers by trying to produce your own sentence, telling us what you are trying to say, and then letting people tell you how to use it in that case.